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Cadmium Plating
Current Usage

| Cadmium plating is used for two primary purposes: |
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| | 1. | To provide
sacrificial corrosion protection to steel components. |
|
| | 2. | To provide galvanic compatibility
between electronegative materials such as Al and Mg, and more noble materials
such as stainless steels. |
|
| Cd plate is
normally chromated with a typical hexavalent chromium conversion coating. |
|
Common Applications |
Versions of Cd Plate |
Specifications |
Corrosion Protection
High strength steel landing gear
High strength steel actuators
Steel fasteners (bolts, rivets)
Electrical connector shells
Galvanic Compatibility
Stainless steel actuators, sensors
Rivets for AL aircraft skins |
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Bright Cd for low strength components
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LHE (low hydrogen embrittlement) Cd and TiCd for high strength steels
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Brush Cd for touch-up and repair
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MIL-STD-870B (inactive)
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MIL-STD-1500 (LHE Cd, inactive)
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AMS 2401 (LHE Cd, inactive)
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QQ-P-416
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MIL-C-8837B vacuum Cd
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AMS-C-8837 vacuum Cd
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AMS 14198·79 (TiCd)
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ESOH Issues
Cd is a heavy metal cumulative poison and a probable (Class B1) carcinogen. Cd plating chemistry involves the
use of several toxins. Cd is
deposited from a cyanide bath and post-treated with chromate sealant. Cd, chromate, and cyanides are all
heavily regulated because of their toxicity.
Cd regulations:
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EPA: Limit 5ppb
in drinking water
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OSHA: Cd
PEL is currently 0.1mgm-3 for fumes, 0.2mgm-3 for dust
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European rules
(ELV, WEEE, RoHS): 0.01wt% limit in electrical and electronic products and
vehicles
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European REACH:
Cd plate not permitted on many products, including vehicles; except aircraft,
electrical contacts, and critical safety equipment
Exposure
Personnel may be exposed during manufacture, depot overhaul, and operational level touch-up and repair.
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OEM and depot
personnel may be exposed to Cd and As in liquids and mists used in plating and
to Cr6+ in chromating processes. Emission controls, PPE
required.
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Maintainers are
exposed in corrosion control and localized touch-up (brush Cd). PPE
required.
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Cd can be leached
during washdown of systems containing Cd-plated components (e.g., engines),
producing hazardous waste
Alternatives,
Applications, Status
Various
alternatives are in production for different military and commercial
applications. All of these
alternatives
are commercially available with the exception of the LHE ZnNi.
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Most Common Cd Alternatives
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Examples of Authorizations and Implementations
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Specifications
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Corrosion-resistant (CRES) materials –
stainless steels, Ti, composites
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Engine components, fasteners, connectors
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Various
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IVD Al (Ivadizing), pure evaporated Al
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Used by OEMs and several depots
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MIL-DTL-83488B
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Electroplated Al (AlumiPlate)
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F-22, F-35 landing gear and other structural
components, connectors
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MIL-DTL-83488B
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Arc or flame sprayed Al
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Bombardier Dash 8
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MIL-DTL-83488B
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Metallic-ceramic coatings (e.g., SermeTel and
equivalents)
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F-22 landing gear
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MIL-C-81751C
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Zn- and Al-filled spray and dip-spin paints
and ceramics
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Commercial automotive fasteners
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Numerous automobile manufacturers
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Acid ZnNi
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Suitable only for low strength alloys
(<160ksi)
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AMS 2417E
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LHE alkaline ZnNi
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Undergoing qualification testing
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None
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